Garudapurana 1.15.96

1.15.96

prāṇo 'pānastathā vyāno rajaḥ sattvaṃ tamaḥ (590)śarat /
udānaśca samānaśca bheṣajaṃ ca bhiṣak tathā //

the outgoing breath, downward breath, diffused breath; passion (rajas), purity (sattva), darkness (tamas), autumn; / ascending breath, equalising breath, medicine, and physician;